Yttrium doping of Ba0.5Sr0.5Co0.8Fe0.2O3-δ part II: Influence on oxygen transport and phase stability

Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ (BSCF) in its cubic perovskite phase has attracted much interest for potential use as oxygen transport membrane (OTM) due to its very high oxygen permeability at high temperatures. However, performance degradation due to a sluggish phase decomposition occurs when BSCF is operated below 840?°C. Partial B-site substitution of the transition metal cations in BSCF by larger and redox-stable cations has emerged as a potential strategy to improve the structural stability of cubic BSCF. In this study, the influence of yttrium doping (0…10?mol-%) on oxygen transport properties and stability of the cubic BSCF phase is assessed by in situ electrical conductivity relaxation (ECR) and electrical conductivity measurements during long-term thermal annealing both at 700?°C and 800?°C. Detailed phase analysis is performed by scanning electron microscopy (SEM) after long-term annealing of the samples in air at different temperatures.     

The Role of Welding Parameters on Achieving a Combination of High Strength and Ductility in Gas Tungsten Arc Welding of Cu–7Al–3Fe Aluminum Bronze

The weldability of aluminum bronze alloys lends it to fabrication of items such as pipes and pressure vessels. Thus, obtaining high strength along with good ductility is necessary. Gas tungsten arc welding of Cu–7Al–3Fe aluminum bronze alloy was performed by variation of some parameters such as shielding gas flow rate, preheat and post weld heat treatment. Optical and scanning electron microscopy along with EDX analysis was applied for different samples. Microhardness measurements and tensile tests were performed to see the effect of these parameters on ultimate tensile strength and ductility of samples.     

On stochastic comparisons of finite mixtures for some semiparametric families of distributions

In this paper, we consider the classical finite mixture model, which is an effective tool for modeling lifetime distributions for random samples from heterogeneous populations. We discuss new results on stochastic comparison for two finite mixtures when each of them is drawn from one of the following semiparametric families, i.e., proportional hazards, accelerated lifetime and proportional reversed hazards.     

Reoptimization framework and policy analysis for maritime inventory routing under uncertainty

We study a maritime inventory routing problem, in which shipments between production and consumption nodes are carried out by a fleet of vessels. The vessels have specific capacities and can be chartered under different agreements. The inventory levels of all consumption nodes and some production nodes should be maintained within specified bounds; for the remaining production nodes, orders should be picked up within pre-defined time windows. We propose a discrete-time mixed-integer programming model. In the face of new information and uncertainty, this optimization model has to be re-solved, as the horizon is rolled forward. We discuss how to account for different sources of uncertainty. We present a rolling-horizon reoptimization framework that allows us to study different policies that impact the quality of the implemented solution, so we can identify the optimal set of policies.     

Intrinsic CFRP-metal-hybrids with rubber interface for the improvement of the damping behaviour

This paper presents an integrated passive damping approach in hybrid metal-CFRP parts for structural applications. In this concept a viscoelastic material is embedded in the joint zone of the hybrid component. To examine the connection strength single-lap-joint specimens were produced and tested and the influence of the used material combinations, different surface structures, and different process parameters i.e. the moment of cross-linking were evaluated. Afterwards, the metal-CFRP hybrids were tested in quasi-static tests to assess their connection strength and failure behaviour. Dynamic cyclic tensile tests with step-wise increased loading conditions were performed to determine the specimens damping behaviour and to estimate their fatigue performance. Finally, these results are compared to a state of the art metal-CFRP hybrid with rivets connecting both materials.     

Surface pre-treatment and its influence on electric functionality and the formability of screen printed steel sheet

Industrial development focuses on multifunctional components due to rising requirements regarding e.g. light weight and security. A beneficial possibility to extend the functionality of structural components produced by metal forming is the usage of screen printed metal blanks. During the printing process insulating and electric inks are applied. The examined printed layer structure consists of three insulating full area layers and one conductive layer in the form of strain gauges. The two applied inks are solvent-based and printed with a half-automatic machine. To improve the adhesion and electric functionality, the impact of different mechanical and physical surface pre-treatments on the electrical characteristics is investigated in tensile tests. In particular, abrasive peening, ball peening, grinding and polishing (mechanical) and in addition plasma and corona technology (physical) were utilised. Contrary to expectations, the surface pre-treatment does not affect the adhesion to the steel sheet. The cracking of the printed strain gauges takes place prior to the delamination of the coating. Explanatory models are elaborated. They are based on the measurements of roughness, surface energy, edge sharpness and the electrical resistance of printed conductive structures before, during and after forming.     

Transparent Nanocrystalline Glass-Ceramic System for Organic Pollutants Degradation

Because of the superior photocatalytic activities of nanocrystalline TiO₂ and ZnO under UV irradiation, they were embedded into the glass system (SiO₂, TiO₂, ZnO, B₂O₃, Na₂O, K₂O, P₂O₅, Li₂O and BaO) to provide easy separation from the aqueous system. Different contents of TiO₂ and ZnO have been investigated. Conversion to glass-ceramic materials was carried out by heat treatment at 450 °C, which is the onset of the nucleation peak according to the differential thermal analysis (DTA) result, for different times. This heat treatment regime preserves the transparency of the prepared materials in the visible region and good absorption in the UV region. The high content of TiO₂ or ZnO caused an improvement of microhardness of the prepared materials, though the presence of the two oxides with the same ratio decreased the microhardness values. Photocatalytic activity of the prepared glass-ceramic materials was investigated according to their efficiency for the degradation of humic acid (HA), the major precursor of disinfection by-products (DBPs), from water. All samples were proved to be photoactive with different extents. Four hours heat treatment at 450 °C appears to be the best conditions for the development of TiO₂ and ZnO crystals leading to better photocatalytic activity.     

Efficient PL Emission from p-type Porous Silicon: A Comparative Study for Selection of Effective Anodization Parameters

The physical mechanism of highly efficient photoluminescence (PL) emission from p-type silicon is described by a comparative study of the effectiveness of the etching parameters in an electrochemical anodization technique. Two series of porous silicon samples were prepared in a combination of anodization current and time, to maintain the total amount of anodic charge transfer constant. Photoluminescence studies show that irrespective of the amount of charge transfer, the samples prepared with comparatively higher current density show an efficient PL as well as stronger blueshift in the emission energy vis-à-vis the samples prepared for longer durations. An overall decrease in crystallite size, as estimated by Raman spectral analysis, was observed for both series of samples with the progress of charge transfer. Comparative analysis shows a marginal difference in crystallite size for both series of samples in the initial state of charge transfer, whereas major differences arise at higher values. This is explained with the formation of silicon suboxide on the porous surface at higher current density, leading to initiation of side wall reaction, and higher reduction rate in crystallite size as well as strong luminescence due to the carrier quantum confinement effect.     

An Investigation of Mechanical Properties of Polyurethane Nanocomposites with Various Silicas: Experimental Study and Modeling of Finite Deformation Response

It is well-known that polymer nanocomposites can bring about superior mechanical, thermal, optical, physical, and chemical properties in comparison with pure polymers. In this study, different contents of unmodified silica nanoparticles (Si-Un), surface modified nano-silica by octylsilane (Si-OS), and surface modified nano-silica by polydimethylsiloxane (Si-PDMS) are added to the polyurethane (PU) matrix and their effects on the physical properties of the polymer examined. The experimental results indicate that most of the nanocomposites have a higher tensile strength and elongation. In addition, hyperelastic energy function models have been used to model the stress-strain relation of the nanocomposites. In this study, Mooney-Rivlin, neo-Hookean, Rivlin general polynomial, and Davies-De Thomas (DDT) models have been investigated, possessing respectively, two, one, eight, and three constants to be determined. The differential evolution (DE) optimization method, a strong heuristic optimization algorithm, has been used to find the constants; in which the absolute summation of the differences between the models’ predictions and experimental data is taken into account as the objective function and the models’ constants are considered as the decision variables. Moreover, equation constants are found by using regression, an indicator of DE optimization superiority. The results show that even though the Rivlin general polynomial model provides the most accurate prediction, the DDT model, consisting of three constants, can be considered as the most acceptable one.